A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima

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A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima

Da casca do tronco de Hymenaea courbaril var. altissima (Ducke) foi isolado um novo entclerodano na forma de éster metílico, após esterificação com diazometano, o (-)-(5R,8S,9S,10R)clerod-3-en-15-oato de metila. Foram isolados também dois ent-labdanos conhecidos: o (-)-copalato de metila e (-)-eperuato de metila. Do extrato AcOEt do epicarpo foi isolado, após esterificação com diazometano, o (-...

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Hymenaea courbaril var courbaril seed xyloglucan was efficiently extracted with 0.1M NaCl, followed by ethanol precipitation (yield=72±5% w/w). Its amorphous structure was identified by the pattern of X-ray diffraction. The monosaccharide composition was determined by GC/MS analysis of the alditol acetates and showed the occurrence of glucose:xylose:galactose:arabinose (40:34:20:6). One-(1D) an...

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Morphological analyses suggest a new taxonomic circumscription for Hymenaea courbaril L. (Leguminosae, Caesalpinioideae)

Hymenaea is a genus of the Resin-producing Clade of the tribe Detarieae (Leguminosae: Caesalpinioideae) with 14 species. Hymenaea courbaril is the most widespread species of the genus, ranging from southern Mexico to southeastern Brazil. As currently circumscribed, Hymenaea courbaril is a polytypic species with six varieties: var. altissima, var. courbaril, var. longifolia, var. stilbocarpa, va...

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Three new clerodane diterpenes from Polyalthia longifolia var. pendula.

Three new clerodane diterpenes, (4→2)-abeo-cleroda-2,13E-dien-2,14-dioic acid (1), (4→2)-abeo-2,13-diformyl-cleroda-2,13E-dien-14-oic acid (2), and 16(R&S)- methoxycleroda-4(18),13-dien-15,16-olide (3), were isolated from the unripe fruit of Polyalthia longifolia var. pendula (Annonaceae) together with five known compounds (4-8). The structures of all isolates were determined by spectroscop...

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ژورنال

عنوان ژورنال: Journal of the Brazilian Chemical Society

سال: 2002

ISSN: 0103-5053

DOI: 10.1590/s0103-50532002000300015